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The Pound (lb):

The pound or pound-mass is a unit of mass used in the imperial, United States customary and other systems of measurement. Various definitions have been used; the most common today is the international avoirdupois pound, which is legally defined as exactly 0.45359237 kilograms.

The unit is descended from the Roman libra (hence the abbreviation "lb"). The English word pound is cognate with, among others, German Pfund, Dutch pond, and Swedish pund. All ultimately derive from a borrowing into Proto-Germanic of the Latin expression lībra pondō ("a pound by weight"), in which the word pondō is the ablative case of the Latin noun pondus ("weight").

Source: https://en.wikipedia.org/wiki/Pound_(mass)

The Kilogram (KG):

The kilogram or kilogramme (symbol: kg) is the base unit of mass in the International System of Units (SI), and is defined as being equal to the mass of the International Prototype of the Kilogram (IPK, also known as "Le Grand K" or "Big K"), a cylinder of platinum-iridium alloy stored by the International Bureau of Weights and Measures at Saint-Cloud, France.

The kilogram was originally defined as the mass of a litre (cubic decimetre) of water at its freezing point. That was an inconvenient quantity to precisely replicate, so in the late 18th century a platinum artefact was fashioned as a standard for the kilogram. That artefact, or an exact replica thereof, has been the standard of the unit of mass for the metric system ever since.

Source: https://en.wikipedia.org/wiki/Kilogram